With world No 2 Rafael Nadal bringing down the curtain on the scheduled matches, taking on the United States' Donald Young, a few more chapters in the quest for this year's titles will be written by the end of the day.
Sixth seed Konta, 26, lost to 21-year-old Vekic, ranked 58, in the final of the Nottingham grasscourt tournament last month.
"It's another opportunity for me to try and find a way to come out on top this time," Konta told reporters about the match-up after her first-round win over Hsieh Su-Wei.
Twice champion Murray, who has been suffering with a sore hip, has already dispatched one player with an armoury of unconventional shots, Kazakh Alexander Bublik.